Here's a ranked listing of Fonts.com Web Fonts' top 100 most used Web fonts for May 2012:
Neue Helvetica
Trade Gothic
Futura
DIN Next
Frutiger
Gill Sans
Avenir
Helvetica
Univers
ITC Avant Garde Gothic
Neue Frutiger
Futura T
Slate
Trade Gothic Next
New Century Schoolbook
PMN Caecilia
Avenir Next
Neo Sans
DIN 1451
Linotype Didot
ITC Lubalin Graph
Linotype Univers
Frutiger Next
Arial
Garamond 3
VAG Rounded
Neue Helvetica Arabic
Harmonia Sans
Times
Monotype News Gothic
Yakout
Bauer Bodoni
Soho
Heisei Kaku Gothic
Laurentian
Soho Gothic
Gothic
Rockwell
Eurostile LT
Egyptian Slate
Cachet
Glypha
ITC Franklin Gothic
Memo
Century Gothic
Monotype Grotesque
Plantin
Akko
Camphor
Neue Helvetica eText
Sackers Gothic
Plate Gothic MT
News Gothic
ITC Officina Sans
Clarendon
ITC Stone Informal
Monotype Modern
Aachen
Ocean Sans
Amasis
FB Han Gothic
Bell
ITC American Typewriter
Azbuka
Consolas
Andale Mono
MYuppy
Droid Sans Mono
Frutiger Serif
Eurostile Next
Linotype Feltpen
Walbaum
Optima
ITC Garamond
Mitra
Wiesbaden Swing
Baskerville
Neue Haas Grotesk
Adelle
ITC Conduit
Bembo
Monotype Garamond
Impact
ITC Kabel
ITC Franklin
Neuzeit Office
Calibri
Rotis Sans Serif
Gazette
ITC Legacy Serif
Klint
ITC Officina Serif
Abadi
ITC Caslon No. 224
Loft
Museo
Neo Tech
Calvert
P22 Underground
Bodoni LT